Volt-nuttery is a long and dangerous path, even with a 3458A, the 8 1/2 digits is a bit of a stretch. The standard 3458 is 8ppm/yr ie close to 5 digits of real 'accuracy', the 8 1/2 refers to transfer repeatability. Cabling, connectors, thermal issues, EMI etc all play merry hell with your sense of absolute accuracy in the region of a handful or so of uV in the 5-10V DC range ie 6 digits of true accuracy.
My 3458A is in cal, I have 16 LTZ references. Nine of them have been switched on continuously (UPS) for about 15 months or so. The most recent lot - about 5 months.
To do a good 'measurement' run takes about a day to 'warm up', an hour of switching off almost everything in the shack and cleaning the terminals/cables.
Even then, 3 or 4 of the better references will reliably be within the +/- 2 to 4uV of what I think they should be.
I have been surprised how good a bog standard 34461A has been. Often within 10 to 15uV - but I didn't record it's results like I did for the 3458.
An interesting and ongoing experiment.
Rob