At some point you need to reference it against a standard. But the big question you have is can you create a standard that has no other reference but itself, like the JJ is for volts in the world?
JJ compare themselves against frequency standards, and making conversions is the key. In this paper, you see 2 separate JJ setups compared against a single microwave source and shows the degree of agreement.
http://iopscience.iop.org/0026-1394/31/1/007Since you cannot do a similar task with semiconductor references, what you can do is the old-style metrology methods. To make a long story short you need to track the drift of your reference vs time. The curve will show cyclic variations with climate, and a long term variation over its mean. You can then reference your measurement against itself, to the past, and knowing at the zero point, you were in calibration against the standard, estimate the variation from the true value. This creates a level of certainty and thus, your standard is now expressed both as a value, and a degree of certainty; what is purely physical now becomes partly statistical.
Referencing the photo, you cannot use a reference so young that it drifts in mean as is A, either up or down in value. You want drifts like b. Choose a type of reference design that reduces the width of c. Your stable reference should give a mean value of d and the certainty is effectively the width of c.
The X axis is time, the Y is volts.
The graphic is a simplification, the real data can be hard to decipher until you amass enough data to see the forest from the trees. An example of real data, taken from a volt nuts post.
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I would really like to have all my meters dead-on accurate as well as precise, but I don't really know all I need and how to build myself a calibration schedule and procedure.
Total side note: is it obscenely difficult to set things up so your own home lab can procude NIST traceable calibration certificates itself? (as a non industry hobbiest, I know nothing or little avout this)