Any small wall wart with an input range of 100-240VAC is going to be SMPS, and they all will work on 220VDC for sure. Only linear wall warts I have seen in the last decade were Siemens early Gigaset ones, which have a moulded transformer, and a 9VAC output, with a input voltage of 220VAC.
But all from the last decade have been a SMPS, even in the cheapest nastiest nastiest emergency light, where there are some enterprising manufacturers who made a retrofit board with the same footprint as your common Chinese 9VAC 1A ( peak, on a good day, for a few minutes, with a DC resistance of around 20R on the secondary and around 10k on the primary, so ultra poor regulation figures but actually short circuit proof not by design, and with no thermal fuse in the windings either in most cases) transformer that is a SMPS, that I would not use if there is any regard you have for it actually being safe to touch the secondary side.
Those are not the things to test, they pretty much are going to either fail with only minor transients, or just blow up on their own, but the better branded ones you might have lying around in a drawer that are listed and purported to pass a safety standard are the ones to see. Cheapies are only fun if you find that single example that was slipped through by accident as being great, and which will survive an actual IEC test pulse train undamaged.