Yes,you are very unlikely to come across an Amplitude Modulated 100MHz signal "in the wild",except in the Aeronautical service,which is a pretty specialised & highly regulated area,where "just looking at the envelope" would only be a rough check.
When ever I've looked at civilian NAV/COM equipment (from 108MHz to 137MHz) it has never occurred to me to even attempt to look at the RF with a scope, I use a comms test set and spectrum analyser, plus a VOR/ILS baseband generator with an RF signal generator. I'm not sure what the point is of looking at the RF on a scope would be, but I'm happy to be educated! At AF/baseband and IF a scope is certainly of value.
Sometimes,you have to "just run what you brung".
We had a strange problem with an NEC FM broadcast Transmitter.
This Tx had a FET PA driving a big tetrode in common cathode configuration.
There was an output meter on the FET PA,to show the drive to the tetrode control grid tuned circuit.
Using the time honoured "peak the grid & dip the anode" tuning method,we found a seemingly ridiculous situation where more grid drive on the meter caused lower output power.
The FET PA had an adjacent monitor point,so,as it was to hand,I grabbed the 200MHz Iwatsu 'scope & looked at that point.
The problem was immediately obvious----a horrible,peaky waveform,with a high second harmonic component.
The FET PA output meter was a "peak & hold " type----higher peaks from the distorted waveform looked like more grid drive.
All that second harmonic power was suppressed in the anode tuned circuit--hence less transmitter output power!
From then on,we tuned "for maximum smoke"instead!
We had a 7L12 in a Tek 7000 mainframe,so could have used that,but it was hard to get to the monitor point,& I wasn't quite as familiar with the 7L12 as I later became.
In any case,the time domain display gave an immediate insight into the problem.
Apart from that,I had very little occasion to look at VHF RF signals in the time domain.
If your 'scope will do it,it is a very quick way of checking modulation percentage of AM transmitters,but this is mostly done in the MF & HF case.
I feel it is a very savage test of a DSO,asking it to display frequency components with a ratio of 100,000:1.
Looking back,though,we condemned early DSOs because they aliased their hearts out when trying to display
2 fields of PAL video ---that was a ratio of 200,000:1!