I have a somewhat silly question as I looked for a 6.5 Digit Meter myself in the past days.
If I buy a 6.5 Digit thing used it is certainly out of calibration and there's no way I'd have the equipment to cal such a meter myself(service manual of a Agilent 34411A states a Fluke 5720A )
So why should someone for hobbiest purpose getting a 6.5 digit meter ( although the used ones are fairly cheap)
It's a risk you take when you buy second hand. I have a few voltage standards I use to check all my meters, like the DMM check plus, they aren't anything fancy, but it's good enough just to see if you're close enough, also ok for calibrating old 4.5 meters or oscilloscopes.
You also use your other meters to compare. Some folks may use a calibrated 6.5 (or higher res) meter they own and trust to be in spec to calibrate their other meters. There are also profesional voltage transfer standards you can calibrate and use to calibrate your other gear.
DMM check is useful as It basically just gives me a warm and fuzzy that the instrument is not horribly out of spec. I don't have a need for a 6.5 digit meter really, 5.5 is overkill for most stuff I do. The one I own I got it for the THD measurements (keithley 2015) the 6.5 resolution came as a bonus. My Fluke 87 Vs is what I measure voltages with most of the time, and it's good enough.
A meter may not be calibrated, but it can still provide good enough drift measurements if you're trying to measure drift in a circuit over a period of time with a higher degree of accuracy because 6.5 digit meters will have an oven controlled reference with little drift.