If it's defined as exact, there's no such thing as "more exact"!
The sausage effect pushes the uncertainty onto other free variables. Those that are fixed by theoretical relations (like the characteristic of a Josephson junction) also have no uncertainty. Others (like G or k_B) limit the precision of related measurements.
How about a color analogy? Suppose the primary and secondary colors are simply what people call them as; there's no theoretical or absolute definition of "red" or "cyan", they're just what people take them as.
In this state, you know that, if you take about half and half proportions of the color called red, and mix it with the color called green (additive light here), you get what's called yellow.
This is a simple, informal relation: R + G = Y. None of them are really quantitative, it's more like a Boolean statement.
Suppose a Theory of Color is discovered, which fixes the values of R, G and B. And secondary colors are indeed proven to consist of primary colors. It is found that the color that's called "yellow" contains 57% R, 43% G. This proportion is now a measured quantity, in the same way that resistance is a measured ratio between voltage and current.
Suppose the Theory of Color was later refined: it is discovered that, although the above is still true for additive lights, the exact opposite is true of subtractive pigments -- Y + C = G! And because of this, earlier standards which defined colors in terms of primaries only, but which had some bad tolerances (suppose, we can't get a good precise blue from incandescent lamps, so we've always had trouble building precise colors that contain blue), can now be defined in terms of pigments (which are now fixed fundamentals of chemistry instead).
Incorporating some of these new definitions, suppose it is found that "common yellow" is 97.3% theoretical yellow, with a little bit of red thrown in. It's like redefining the inch in terms of the meter (1 in == 0.0254 m): it's slightly different from the accepted value, but close enough not to matter in many cases. With an exact correspondence, it no longer matters which format one uses to express their colors; it's just a matter of preference which color system they use.
Now the state of things is such that, colors and mixtures are defined partly by lights and pigments; and that combinations of both can be used to get even more precise standards.
Suppose the Theory of Color is proven complete. Now R, G, B and Y, C, F are fixed theoretical constants: the primary (light) colors are emissions at certain wavelengths, and the secondary (pigment) colors are absorptions at the same wavelengths. There is no longer any uncertainty whatsoever in the pure colors; and any color in the rainbow (or more importantly, that we can sense visually) can be expressed in any desired amount of precision.
This is the future that physical standards aim for; whether it's theoretically possible (provable completeness) is still up for grabs. It is known that a certain limited set of physical constants (as measured parameters rather than fixed definitions) is necessary. Whether those are "top level" (spooky quantum parameters like h and c) or derived parameters (like the meter), doesn't matter to the theory, as long as the degrees of freedom are conserved.
For more reading, check out alternative dimensional systems, like Planck units -- defining the fundamentals as unity (1.0 exact), and making customary units (like time and length) derived through proportions.
Tim