I don't know about graphite spray exactly (aquadag or similar?), but yes, there are conductive paints to do that.
Had a project about four years ago, customer wanted a system with a power supply, control box, and IO fanout box(es). They insisted on putting USB inside unshielded cables. We warned them about that...
Actually, the cable was shielded, because pretty much every multiconductor cable has foil in it already, but it's a lot more work mating that up to a metal connector, versus using cheap plastic connectors and not bothering with shielding at all. (We're talking IP rated circular connectors here.)
Long story short, we changed the connectors to metal shell, connected up shields and grounds, and put in shielded boxes where possible. The customer wanted a $50 IO/fanout box, we delivered a $200 box.
Very nice box, it was; IP66 (or thereabouts) rated, lined with conductive paint, including the rubber gasket, which surprised me! Nice low resistance, fraction of an ohm, contact resistance dominating the measurement I think. Good for at least 40dB shielding, which was what we needed to pass immunity. Just expensive as sin, like $80
before machining...
Tim