If you want to know how accurate the 732B can be, NIST is using them to certify some (what NIST calls) CJVAs and PJVAs (Conventional Josephson Voltage Array or Programmable Josephson Voltage Array). In a North American Interlaboratory Comparison run by NIST, by using a bank of four 732Bs as the traveling standard, agreement to within +0.022 / -0.018 ppm was achieved. (Using a PJVA as the traveling standard, agreement within 0.0005 ppm was achieved.) Some labs do not need the accuracy, or do not have the space for another JVA to compare against. It was stated that this approximately 0.02 ppm comparison was achieved by developing coefficients for the 732Bs, such as for pressure.
Where I work, we get our 732Bs calibrated using the Fluke DVMP program. They send us one 732B, we make the measurements using our meters, and Fluke gives us a NVLAP certified report. The last report we got had a stated uncertainty of the measurement of 0.06 ppm.
If you want to know how those seemingly continuous comparisons are made on lab 732As or 732Bs, a system already exists that does that (you don't need to build one yourself). We have a 32 channel scanner from Data Proof and VoltRef software from Data Proof. (We got the guarded scanner and I'm glad we did.)