I haven't tried this, but could you use both outputs tied together (== summing them), and have each set to burst (N=1) mode; one with +edge trigger, the other with -edge ? You could then get a + pulse on your trigger rising edge, and a - pulse on the trigger falling edge.
Else, if your triggering is quite slow (say < 1/s), in principle, you could reprogram it between trigger pulses.