Thank you for the responses everybody (though the general assumption seems to be that I've no idea what I'm doing!
)
Yes, I was aware that my measurement approach was not the official way to do it - I don't have access to such equipment. And I did say that perhaps it has a resistance (between two points) of > 11 Gohm but I would expect even a dissipative layer to have some (very high) resistance.
I replaced my probes with two squares of aluminium (around 10cm x 10cm) pressed down with the probes (yes I know - it is not the correct way but it is an approximation).
On the ESD mat (which has a surface dissipative layer) the resistance drops to around 14 Mohms.
The rubber dissipative only mat still reads as > 11 Gohms.
I tried fitting a aluminium sheet under the rubber mat and aluminium square above it. Still > 11 Gohms.
I found this reference :
https://www.gotopac.com/art-esd-resistivitywhich states:
Dissipative materials have a surface resistivity equal to or greater than 1 x 10^5 Ω/sq but less than 1 x 10^12 Ω/sq or a volume resistivity equal to or greater than 1 x 10^4 Ω-cm but less than 1 x 10^11 Ω-cm.
In my effort to get a reading I found an Al block which is 10cm x 11.5cm x 6.5cm and has a fair weight (probably more than 5lb).
I placed an Al sheet (clip board) underneath.
I measured the thickness of the rubber mat as 3.1 mm using precision calipers (difficult to do because of a lip).
Still > 11 Gohm so the bulk resistivity is greater than 11E9ohms * 10cm * 11.5cm /0.31 cm = 4 x 10^12 ohm-cm
I also tested the meter on a series connection of 1% resistors 5G + 3G + 2G + 1G = 11G and the meter reads 10.8G which I think is in spec.
So despite my dodgy methodology, I persist in thinking that the dissipative rubber mat is not very dissipative. By my (admittedly flawed) calculation the bulk resistivity is at least 40 times the maximum for a dissipative material.
I admit I've not done a very precise measurement of surface resistivity because I lack the right probes.
Unfortunately I don't have a piezzo electric lighter handy to try that test.
I'm not trying to get any super accurate measurements here, I just feel a dissipative mat should register some sort of reading. Unfortunately I don't have any other purely dissipative rubber mats around to compare - my other mats are all of the standard multi-layer ESD variety.