I just got one of the 9V batteries from DX, same as in the link posted earlier in this thread. I charged it up in my 9V Lithium/NiMH/Nicad charger and then used one of my iChargers to discharge and measure the capacity. Peak voltage after charge was just over 8.4V, when the battery arrived it read 7.731V on my 87V.
Setting discharge to 0.2A, I got 420mAh by the time the voltage dropped to 7.000V. Continuing on... I ended up getting 484mAh total when the internal battery protection circuit kicked in at ~6.25V At this point the battery reads as an open circuit, 87V shows 0000 when measured. Placing the battery back into the charger, the protection circuit reset and allowed the charger to begin charging again.
So... if using these types of batteries, there are a few quirks one must be willing to accept.
1. Low voltage vs primary cells. Many devices will be quite happy to run on 6.x to 8.x, but not all.
2. If using the cell until it goes dead, be aware that it goes dead *suddenly* when the protection circuit kicks in.
3. Lithium Ion chemistry is not the best for little used devices. A fully charged Lithium cell will deteriorate faster than one that is partially charged.. So placing one of these 9V batteries, fully charged into a device that has little draw or is not used often will cause the battery to loose capacity faster due to the voltage stress.
4. Compared to NiMH, LiIon has a shorter lifespan and does not store well.
5. LiIon with it's low internal resistance can cause problems should the battery short out by contacting something conductive by accident, and this could result in a "vent with flames" event. I do not know if there is short circuit protection in the internal protection device. All that is mentioned on the battery is that one should not draw more than 0.5A in use.
6. Cell balance. This is an issue unless the internal circuit manages it. Unlike NiHM or Nicad where trickle charging is used to bring the cells into balance, trickle charging is unsafe with Lithium based cells. They should be charged until max voltage is reached and then the charger should stop charging. Some do trickle charge and this simply damages LiIon cells. Balance charging LiIon batteries is done by monitoring each cell's voltage and discharging the highest voltage cells periodically until the low cells catch up, or each cell can be charged separately through it's own dedicated circuit.
For me, too many downsides to switch to this type of cell. Yes, the capacity is nice, but most of my devices that use 9V batteries are very low drain and my 9V NiMH batteries get swapped out with freshly charged ones twice a year, January 1st and July 1st. Easy to remember and no worries if a battery chucked in a drawer shorts out against a spoon or fork. If I used things like paint ball guns or some such, that have high current demands, then perhaps LiIon, despite it's drawbacks, might be the way to go.
Regards
Christian