Chipquick will work here, as it will allow you to flood the whole connector at a single unit then simply pull it out in a single pass. A hot air unit also works well, just get some sacrificial aluminium foil shields held down with Kapton tape to protect the rest of the board. A broad chisel tip on the iron as well helps, then after the connector is out clean the pads with braid then you can put the new pin header in the holes and solder it down. for those I have a soldering handle for my unit that has a flatpack tip on it, a broad Weller tip that does a good job of melting around 15mm of solder at once.