sorry, didn't read carefully enough.
Maybe you can post some screenshots showing the ripple. Which frequencies does it contain? Is it also present at the buck converter's input? What happens if you remove the ESD mat? PCB layout will also play an important role here. Is the buck converter's power inductor shielded? It may also be coupled into the converter's feedback path.
I recommend not to add LC filters after the converter output, as this will create a pole at its resonance frequency, which will amplify every load modulation at this specific frequency, instead of damping it. If you want to add further filtering, I would add a ferrite instead of an inductor. You only need to care about frequencies that are beyond the converter's bandwidth. Everything below that is handled by the control loop. Depending on the buck's design this is in the order from kHz to tens of kHz.
What I would do next is take the clip of my probe and remove the ground lead, turn up vertical gain on the scope, and use it as E field sniffer. Not as good as a spectrum analyzer but in most cases I can find possible sources of radiation. You can also probe H fields to some degree by connecting the ground clip to the tip, but that is not very sensitive.
Next would be adding copper foils soldered to circuit ground.