Note that *ANY* filler, applied in a thin enough layer between two approximately flat surfaces in contact is better than nothing as very thin air gaps are notoriously poor thermal conductors. If you don't have heatsink compound, a small dab of any high temperature grease, or even toothpaste will do, but in your application its probably a good idea to avoid ones containing electrically conductive particles due to the future trouble stray traces are likely to cause. e.g. avoid graphite grease, copper and aluminum antiseize, and Noalox and similar zinc loaded electrical jointing compounds.