Ugghhh, shitty datasheet doesn't even know what it's talking about.
Absolute Maximum Ratings
VDD 3.5-5.3V
...
Electrical Characteristics (VDD = 4.5-5.5V)
If you didn't already notice their characteristic measurement spec is performed under conditions
exceeding the absolute, you might've noticed they're unsafe when powered down. Yep, can't ever have VDD less than 3.5V. It'll explode if you drop below 55... or something. (Bad movie reference.)
Also like how "typical" is abbreviated "tpy".
I would wager a guess that these are HCMOS compatible, and as such, fine to 7V. Beyond that, they may or may not fail gracefully. If not, well, if I were you, I'd feel rather ashamed busting 100 pounds on crap like this...
Anyway,
That's a good way to do it, though I've been warned about slowly rising conditions (not just marginal voltage, but slow dV/dt as well). Zeners aren't terrifically accurate, and lower voltage devices are leaky. You can compensate that some with the G-K resistor, but leakage remains temp dependent.
A more accurate way is to use a TL431 as a ref + comparator (or a TLV431 would work at this voltage -- save about a mA), and add positive feedback (using a resistor divider into the "anode" pin to fake the + input, or an outboard transistor to invert the signal and feed back a little into REF -- which is also better for finally driving the SCR) so it snaps on at a fixed level, regardless of dV/dt.
Tim