Beautifully done! I'm very envious of your mechanical construction skill.
Incidentally, what kind of paint is that? Powdercoat, or just ordinary spray can?
Speaking of pneumatic 'capacitance', it amazes me how crummy all the motor-driven solder suckers I've ever used are. Put the tip on the pin you want to desolder, wait for it to melt, press trigger.... and slooooowly a pump turns on, evacuates the loooong tube, graaaadually begins to pull solder out of the joint... and if that works, you're lucky.
Why don't solder suckers use a large pre-evacuated chamber right behind the nozzle, and a quick-open valve close to the working tip (like yours) to initiate the suck? The objective is obviously to get all the solder out of the hole as fast as possibly, before reduced solder cross section causes big heat sinks (like internal ground planes) to freeze remaining solder. To do that you need to near-instantly expose the molten solder to a full vacuum (30" mercury) with as little impedance to flow as possible. Solder spatter filters should be on the other side of the reservoir, not between the tip and the reservoir. So what if you have to clean solidified solder out now and then.
This is why I prefer the simple mechanical soldapult type suckers - they act fast.
Anyway, the difficult part seems to me to be making a fast-open valve, that still works despite solder dust and spatter. And to get it close to the tip, it will be exposed to heat too.
I think your method would fail in the presence of solder spatters. For one, it's brass, and the solder could stick. Second, it doesn't have the strength to be able to chop off solder spatters that clogged the opening.
I wonder if there are such things as solenoid actuated small PSZ ceramic ball valves, with (say) about 4mm inner diameter?