Dpeends on what exactly you're trying to do, and the sort of charger you're using. As you know most 'chargers' in terms of commercial products are just voltage-regulated power supplies - the charge management circuitry that controls current and voltage is usually inside the product. For hobby RC its a different story, the charger is both the supply and charge management. The battery packs just have the mandatory protection cricuit (back to back FET's, monitors current in, out, and max/min voltage).
For multicell setups there's things like cell balancing to contend with that I'm sure many chargers do just fine, but it also means that there's several connections/voltages that vary to maintain current.
If you are designing this yourself, you will obviously need charging circuitry in the device - unless you plan on having users remove the battery to charge it. So, if you're already designing the charger you'll have a power input from a regulated supply that will probably be converted, using a buck/boost by the charger. In which case a very simple load sharing circuit will do providing your load can cope with the range of input voltages you're planning on using for the charger.
That is, 4S2P = 12.8 - 16.8V (for 4.2V cells) or 12.4- 16.4V (for 4.1V cells). If you have a linear charger then you'll need a supply higher than peak voltage to account for losses, current sense etc.. so say 18V. If you're using a switcher, many can be sepic, or buck/boost, in which case the input voltage range can be above, below, or in the middle of the range, say 12-18V. If the load has its own regulator, then it can cope with this range so the following 'add-on' circuit will power the load whilst also charging the batteries:
http://ww1.microchip.com/downloads/en/AppNotes/01149c.pdf page2.