power efficiency is not my concern for something used so sparsely.
It's not just the efficiency.
If you want to charge the supercap quickly enough, instead hours, you'll need several amps.
With a buck regulator it's easy, compact and keeps everything relatively cool.
Try that with a linear, you'll have a bulky thing requiring heatsink, perhabs a fan...easily getting more expensive than the buck converter.
Plus it'll heat everything up, may affect other components, not sure about the heat effects on supercaps lifetime.
You say the power is not a problem, but it's always nice to be able to reduce the power supply requirements and save some bucks.