You definitely can't use a voltage divider probe, because that consumes current, not charge. A charge will drain away quickly. You need a capacitor divider, which does consume charge (instead of current).
If the probe setup (guard wire and all) has a known and calibrated capacitance, you can measure charge directly as Q = V*C. A "10x" probe would be a capacitor of 9 times the value in parallel, and so on. For measuring the voltage (such as a static charge) on a known capacitor, use the charge conservation equations to determine the charge given to your probe capacitance (obviously, such a method necessarily disturbs the original charge).
To measure static charge or electric field, you need a calibrated capacitance plate of some sort to do the analogous thing. Because the capacitance varies (you're bringing a plate near another), the voltage (but not charge) on the unknown part is only momentarily disturbed.
Tim