A current transformer is a special case of a transformer. In this case, it is a step-up transformer, the primary winding of the current one turn of the power wire passing through.
Its special parameter is the current transfer coefficient. In this case, the output current is indicated for short-circuit, for direct connection the ammeter.
The calculation of 20A:1V may be incorrect, there may be a different combination of the number of turns of the secondary winding and the load resistor.
To get the voltage, not the current, you need to install a load resistor. You calculated it correctly for 100:0.05. Just do not forget that at 100A you will get 6.25V, more current will not work because of the saturation of the transformer.
P.S. Never leave the pins of a current transformer flying. Without load, there can be multiple kV.