I'd just solder the whole thing with hot air if you have the tool.
It's a bit easier to do with QFNs - I tape some cardboard 'guides' (e.g. leftover carrier tape for chip resistors) on to the board with Kapton tape to align the part correctly in one axis, but this would be more difficult with a QFP where pins would be in the way. On the other hand, proponents of solder surface tension will tell you that you just need to bump the chip to get it into the correct place.
Put a little bit of solder on the centre pad. You don't want to solder the entire pad because once you squash the chip down, it'll distribute over the whole pad and you want it to sit flat without any solder squashing out. Alternatively you could coat the whole pad with solder and then wick it off. You really don't need a lot for it to work - just a nice, even, flat layer.
Using flux, apply a little bit of solder to all of the other pads. Clean and flux again, then put the chip in place and heat with air. Squash down and then nudge into place. Clean, inspect and clean up bridges with a wick if necessary.
I find that if I just apply solder to the top of pins with an iron (imagine if you'd just glued a QFP in place), not enough solder ends up between the pin and the pad. Pre-soldering the pads and squashing down is a lot more satisfactory!