Unfortunately those things (biased or bootstrapped clamps don't work in my case. i don't have aux supplies. My system runs off a coin cell (cr2032) and has to run for 2 years.
Bootstrapping the input protection diodes does not require a separate or higher voltage supply but the buffers do draw more power.
All i want is clamp diode that prevents the opamp input to get more than roughly 1.2 volts across it. ( the a/d power rail is 1.8 volts. and i want to protect the input from large incoming voltages such as esd spikes , metallic noise on the cable etc.
What kind of operational amplifier are we talking about?
Obviously it has low input bias current but bipolar input parts (1) include back-to-back diodes across their inputs to prevent base-emitter breakdown from high differential voltages if that is a problem.
With a 3 volt supply voltage, protecting each input with a pair of low leakage diodes like the mentioned 2N4117 JFET or a 2N3904 base-collector junction which go to the supply voltages is usually sufficient if the operational amplifier's internal protection diodes are not. Add resistors at the inputs and also between the protection diodes and the operational amplifier inputs. The later resistors also isolate the capacitance of the diodes from the inverting input which would otherwise reduce phase margin. Do not make the resistors any larger than necessary.
problems : The power rails are off when not sampling ... so protection would not work (the bias voltage goes to zero so the diode would turn on... which would pulls current from the sensor, a current which is larger than the 1uA. which is a nono... the more current i pull the faster the sensor ages. it's complicated. this thing is a based on an electrochemical reaction. draw more current and the reaction speeds up : eating away the electrodes in the sensor...
Unfortunately i'm not a liberty to give more info on the sensor. Suffice to say it is made for a max current of 1uA into a 1M sense resistor. if you lower the resistor value then the current delivered by the sensor will increase and that ages the sensor. It is also not allowed to send current into the sensor as that destroys one of the electrodes due to an electromigration process.
This bloody thing is made for a 1meg load and gives 1 volt at full reading ( actually 0.98 volt). you can lower the resistor but that comes at the price of a shorter lifespan. There is some passive circuitry inside this sensor in the form of a resistor bridge. i don't have acces to this as the whole thing is potted... otherwise i would stick my signal conditioning in there ... and clamp in a low impedance domain but that doesnt work.
That sounds a lot like a standard cell. They have similar requirements. I am not recommending you do this but the Linear Technology LT1012, LT1008, and LT1097 datasheets show an example where a depletion mode MOSFET with its gate tied to the positive supply is used to disconnect a standard cell from the operational amplifier input so removing power does not damage the cell. This would be difficult to do in a 3 volt circuit.
When shutting off the power to the operational amplifier, why not leave the input protection diodes connected to power? They will be reverse biased anyway.
i already verified that cutting the power rail of the opamp does not change the input current draw of the opamp. it is safe to shut down the entire input path without causing additional load to the sensor.
That is a little odd. Most CMOS operational amplifiers have protection diodes between the inputs and the supply pins so if the supply voltage drops, the inputs end up shorted to the supply pins. The high series input resistance solves this problem but it also solves the problem for the external clamp diodes anyway.
(1) Super beta input bipolar operational amplifiers are suitable for megohm input resistance circuits and have the advantage over many low input current JFET and MOSFET parts of not having their input bias current double every 10C which is important if high temperature operation is a consideration. If you are running on a 3 volt coin cell however, they are probably not suitable do to higher supply current unless the amplifier is being shutoff. They do have the advantage of higher precision and lower noise however.