No.
1) MC34063 has a maximum
peak switch current of 1.5A. For a buck converter, that gives you only 750mA output, even less for inverting.
2) MC34063's maximum voltage is 40V. In your inverting configuration, you have +35V on Vcc and V- on gnd. That means it has 35+|V-| applied across it, with is sure to be more than 40V.
Yes i did have that though of making sure that the voltage comming out of the smps is at least 2v higher then the linear regulators
This is why i thought it might be better with a micro controler so that i can program it all but a potentiometer solution will probably be easyer to use
That offset can be done easily with an op amp.