I haven't tried applying any paint -- but I have used boxes so prepared. (The boxes are awfully expensive, too...) They were... uh, hmm, this kind
https://www.budind.com/pdf/hb1323.pdf but I don't see the EMI/RFI/shielded version available (anymore?), so that doesn't help my point very much... Anyway, the resistance of the coating was quite reasonable, a couple ohms between any two points (DMM probes), including the gasket, which was a bit of a surprise (it has a chalky texture and powdered-brassy color, but it does indeed seal both RF and water!). So, I would expect better than 40dB shielding for most purposes, which is quite reasonable.
So, if nothing else, you should be able to test your own coatings -- the resistance between points should be low, but even if it's not measuring well, that may just be a sign of having bad contact; try making contact with EMI springs, tape, or clamps?
Tim