On the upside, it's only functional insulation, safety regs don't care a lick.
They're basically never going to rate it, because it requires some special circuit to measure across the winding. Which for inductors, is high frequency, so you have all the problems of HF breakdown, and dielectric / partial discharge and all that.
Noteworthy that, if it's a ferrite chip type, it's probably not a good idea to apply much voltage to it -- the pads are terminated on the ferrite itself, which is slightly conductive. NiZn is higher resistance than MnZn, if you can get some idea of what material they used. (Easy enough to tell with a "streak" test, NiZn is brown, MnZn is black. Most likely they're almost all MnZn though.)
And this may still be true even if the leads are simply glued in/on the core, where you might expect they don't have a direct (resistive) path; but at high frequencies you still have the capacitance of that glue layer, which might be quite thin.
If you need it to be correct and safe and reliable, in the design itself, I would recommend getting a custom part made, with insulation rated for the voltage. It can still be enameled, doesn't have to be TIW automatically -- but it also won't be the bog standard material. Can also get shapes/styles to your liking, might as well have it all if it's going to be custom, right?
Hacky solution: use a converter transformer, and just ignore the windings. Flybacks have significant inductance, just shop around for the right one. Bobbin affords high core isolation, and presumably the wire is rated for at least as much as it is (a few hundred peak, if maybe not 600). Will be a bit bulkier, and much more expensive, than needed.
Tim