Both of those fluxes will work properly to 500C IME (500C is the max temp on my Quick 861DW). And these two particular fluxes are also compatible with one another, so no issues there.
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If the flux is turning into a dark baked on crud, then you're staying on the joint too long. Same would happen with any other flux that's heated too long.
As others have mentioned, if you're having to crank your iron to make high demand joints, then you should:
- make sure you're using a tip with sufficient thermal mass
- check the actual tip temp vs. set temp, and calibrate the station if necessary
Otherwise your iron just isn't really up to the job and you're running a risk of damaging the PCB by cranking the temp (i.e. time to get a better station).