A regular boost converter will do what you want. When the input is 4.8, it will do a very short boost to 5- low duty cycle and could be low peak currents. When Vin is >5v + diode drop- won't run. If you use a stout schottky for the boost rectifier, V drop will be about .2v so will be boosting ocassianally. A PFM or similar will work best. A constant frequency PWM will try to boost with diminishing duty cycle near zero. Sepics will work but you'll have to spend some time getting them stable, not a great solution if you're operating right at the crossover. The other option might be to do nothing- if full load is unusuall and high line doesn't matter, let it roll.