I'm really surprised it isn't working as a simple point-multi point "cable replacement" type scenario. I use them like this all the time, for timing critical protocols, with upto a hundred or more peers. I haven't used the 2.4 s2 units specifically, but the s1 pro, and every variant of the 900 pro, s3, and Xsc. Packet sizes are typically 6 to 12 bytes and repetition rates in excess of every 400ms ( of course things slow down a bit if running at 10k OTA though ). Any chance you could set them up as p2p, save your config and paste the contents of your .pro here?
To the user of the synapse units.....I'm glad you managed to get them working to suite your needs. I had a play with them a year or so ago. They looked impressive on paper, but for me failed to live upto expectations in so many ways. Maybe they have matured somewhat.