I am currently in the process of writing an emulator for an MCS-48 compatible microcontroller and considering adapting it for the UPI-41.
From what I know, certain CMOS MCS-48 and UPI-41 devices implement additional hardware functions and/or additional instructions which can include software control for power saving; in addition, certain instructions can differ between such devices within their respective families.
The manufacturers (other than Intel) of such devices with additional and/or modified opcodes I know of are OKI (e.g. MSM80C49), NEC (e.g. uPD80C49 and uPD80C42), Toshiba (e.g. TMP80C48) and Philips (e.g. PCF84C00) - do you know of any other manufacturers (and MCS-48/UPI-41 devices thereof) with such characteristics?