The spectrum depends a lot on what kind of tesla coil it is. A big rotary spark gap tesla coil run at high power to produce lots of corona discharge will cause noise all over the spectrum, not just at its resonant point(Tho still be by far the most powerful there). If you have a solid state or vacuum tube based tesla coil run at low power and no modulation you will get only a single sharp peak of RF power at its resonant frequency, acting as a powerful CW radio transmitter.
Checking the resonance while its off is easy. You just put a loop of wire around the tesla coil and connect it to a network analyzer or any other piece of equipment that's capable of measuring the return loss on an antenna. When you feed the resonant frequency into that loop its energy should be sucked up by the secondary coil and radiates out so you get very little reflected signal back out. When its not at the correct frequency the RF power you put into the loop of wire will simply return back to your equipment showing a lot of reflected power.