Thanks for your feedback!
Perhaps I was slightly unclear - the PTC heater will remain in use, but I do not need the 5V regulator to be placed together with it.
However, using a higher voltage might cause the 5V regulator to dissipate a larger amount of energy and that may cause heating issues - I'll see.
Actually, the temperature sensor will have some wires to extend it to be inside the enclosure for the resistors (I have some insulating fiber/ foam material)
As for a metal case, I will probably use an extruded aluminium one.
The ground terminal is likely connected through external wires.
The socket was chosen because some 24V lithium battery packs, as well as most power plugs use this type of connector to connect.
I could consider to break it out and use wires directly, I suppose.
Though I haven't figured out a good way to keep it on continuously.