Hello,
to calculate the error budget is quite easy.
First, you have a 2V range, i.e. up to 1.999 999V display, and its resolution is 1µV.
10 digits (LSD) are therefore 10µV.
4ppm of a 724mV reading are 2.9µV, so the total error would be +/- 12.9µV. (I don't like the term 'accuracy')
That is equivalent to about 18ppm error of you measurement.
So what's your test problem, now?
Frank