Replacing the 40k by a VHP 101 and others by better resistors will certainly help. However, improving the 3458A data sheet values (, accuracy over time/aging, drifts) formally so that it can be used in traceable (not even ISO certified) cal docs will be another story. It seems quite impossible to do that, not knowing the exact propagation and thus impact of any such design change.
That's an interesting question.
In fact, HP already improved the 3458A over the years, at least by assembling the VHP101 from about 1995 onwards, giving probably 0.3ppm/K and < 1ppm/yr. stabilities.
But they never updated the datasheet, and also the Transfer Accuracy for Ohm mode is still missing. (Can be found for Fluke 3458HFL)
If you list the DCI datasheet parameters and the T.C.s of the different resistors side by side, you easily see, that both were correlated.
The 40k resistor is related to "T.C. With ACAL", the other resistors relate to "T.C. Without ACAL".
Bias current and thermal offset voltages mainly determine the "ppm of range" parameter.
See table below, as-is, and possible improvement.
So any improvement in the resistors specification will directly improve the datasheet.
To get a reliable, metrological clean characterisation, one would simply apply the GUM:
http://www.nist.gov/itl/sed/gsg/uncertainty.cfmYou may determine A-type uncertainties, by measuring the STD of the different DCI ranges.
For the systematic B-type errors one would measure or estimate the range-to-range transfer uncertainty of the 3458A, and the real T.C. by changing its inner temperature.
An external precision current source would be required.
For ACI, a comparison of the frequency behaviour of the old and the new resistors could be done, and then the A-type and B-type uncertainties, of course. That's much more sophisticated, than DCI.
Frank