Sorry for not being clear, I meant the solder had a different surface "finish" i.e., it looks like a different type of solder. Maybe an avenue to explore, along with the reflow curve.
Their reflow curve recommended on their datasheet looks pretty standard. But, they didn't mention anything on the paste itself other than it should be lead-free.
Are you able to remove one and confirm that the module hasn't actually shorted within the module itself?
To me it seems odd that that is the only net experiencing shorts. The solder balls don't look excessive to me.
Are you using a low temp paste?
Have you tried removing the paste from a few of the pads nearest the V_batt pads?
Or a short somewhere else, though I assume you have eliminated everything to end up at the module..
I have tried in the past, by the time I have the amount of heat applied on the board, the FR4 started to melt. The center pad is holding the module to the PCB too strongly I guess. No, I'm not using a low temperature paste. I did tried once removing he outer most ring GND paste and the module does work although not reliably. But, in the sense it doesn't short. This was in the 1st revision of my prototype where the paste opening was 95% of the pad size. In the case where other parts of the circuitry could have shorts, I have also removed them totally before.
If you've already shrunk your paste apertures, I'd try a thinner stencil.
I think a 0.1mm thickness would worth the try.
The gap between the centre GND pads and the left/right pads looks smaller than the gap to the top/bottom pads.
So why are the shorts not happening at the sides?
As SMdude says, is the short in the module?
The module is not symmetrical, more like a rectangle. That's the odd part, why not short the pins to the left and right?
There are 2 variation of the module actually, one the 3G version and the other is 2G version. They are pin compatible. But, the 2G module body is what you would expect from a module (metal can on top, and visible FR4 PCB at the bottom). However, the 3G version doesn't look metal at all (it's some coating I guess). If you do a continuity test around the 3G module except the bottom part without pads, it's all connected to GND even on the sharp edges. The individual non-GND pads obviously is not shorted to GND.
But a 30% mount issue as reported by my distributor really say something is not right somewhere...
And it ain't cheap a piece.
I have had a 50% failure rate for a RF module which was configured on the 433MHz band , the 915 and 868 MHz modules had no issue at all.
The shorts were within the modules itself not on the board I designed. I have seen this multiple times.
RN2483 I guess? I think a 0.10mm looks like a possible solution.
As for now, I'm moving on and ditching the Sierra Wireless series. Even if I managed to figure it out, I believe the yield could still be less than optimal. But, I will reorder a thinner stencil with even smaller aperture to try.