All of the above brings to mind the TU-5 Pulser,which was an accessory for the Tektronix 545B .
This device used a Tunnel diode to create the sharp risetime.
In use,it was driven from the 545B calibrator,which was set to 90v,if I remember
correctly.
The calibration signal caused the Tunnel diode to breakdown after a set voltage level,producing a fast risetime for the part of the rise above that voltage.
In use, 10% to 90% of this section was used to measure rise time.
I had one,but it wasn't much use without the high level calibration voltage,so I gave it away to a friend who was collecting 545s & their accessories.
VK6ZGO