Oh this is gold.
There is no rule that a higher VW cap of the same footprint and capacity is inherently better, as I just found a counter example: 10 uF 1206 size muRata GRM31CR71 series, available from 6.3 to 25VW. All of these are the same thickness, 1.6mm. The 10V edition is noticeable better between about 2.5(!) and 10V, compared to the 25V type.
For other types, like the 0.1uF 0603 size GRM188R71 family, 0.8mm thick, it doesn't matter one iota what VW you use between 0 and 6.3V. There is a worst case difference in capacity at 10V of about 5-7% between the 10V and the 50V specimen. The major differences are near the rated maximum voltages for each type, where you really need the elevated ratings. For instance the 50VW is down about 50% at 50V, while the 25VW is down 45% at 25V.
So tl;dr: You better double check in each and every case, if this parameter is important to you.