The ambient air was indeed certain to have been moist and no I did not breathe into the ball.
Would it need any specific type of plastic (to augment to a sufficient degree) the amount of static within the ball?
I've never seen any data on which types of plastic are the most prone to generating static charge. But I have noticed that some moving coil panel meters with plastic faces are very prone to the needle being deflected when you wipe a finger (or cloth) over the meter face. Sometimes it's possible to get the needle to move as much as half full deflection - and stay there! Breathing onto the meter face clears the charge and the needle goes back to zero.
Other types of moving coil meter don't show this effect at all. And of course it doesn't work on humid days.
Glass-faced meters don't seem to do this noticeably.
The problem with trying experiments to find the best kinds of plastic, is that you'd have to do it in controlled humidity air. Controlled as in ideally zero humidity. Also cleaned plastic, and some way to apply repeatable degrees of 'rubbing'.
Oh hey! I just realized that the LED ball would work a lot better if the inside (surface and all the LEDs in general) were holding a significant charge relative to the outside of the sphere. That way, just putting your hand (at general ground/world potential) next to the sphere would cause a migration of the inside charge to be as close as possible to your hand. And when you let go, the charge would redistribute more evenly again.
I'm pretty sure that's it.
Did the sphere halves screw together and was there something like grease on the threads? It might have been screwed together while the whole thing was at (say) 20KV. When you opened it, you let the magic smoke (literally!) out.
That's quite amusing. Could any product ever rely on a more invisible magic component than a retained static charge?
Edit to add: Ha ha... I'm imagining the assembly line. A platform up on huge insulators, charged up by a van de graph generator. Up on the platform, a row of cute Asian girls assembling the balls, all with their long hair standing straight out in the high voltage manner.