Thank you everyone for the useful replies. It's always worth getting a second opinion and a third, fourth... This design is destined for the SAMD21 but 3.3v is everywhere these days (much lower on the some modern dies, my mind boggles!) but will easily translate to other MCUs like the RP2040 which is also 3.3 off the top of my head. 5v is so last century.
Perhaps I should been clearer that this is a single-rail job and it's only comparing a something passing a voltage at about 50% VCC so the design isn't picky - by, er, design...
and I can't envisage any way it could go all weird on me in such a configuration. Sure I *could* use a negative rail generator but that comes with its own problems. I learned long ago (Art of Electronics, 1st Edition) that relying on hFE is a like wading into a pool of alligators on a warm Florida evening with a couple of carrier bags of fresh chicken, and shouting.... "Come on if you think yer 'ard enough!"
These TL072s might well be a counterfeit - I got some XR2206s recently for a related project and they were (gasp) also counterfeit. I mean is there ANYTHING the Chinese won't copy? The fake XR2206 cark out at about 11.5 volts I'm told but seem to be OK on a 9v battery so that's why I haven't seen the problem. Thanks eBAY!
Hell I even picked up some (cough) germanium point contact diodes (cough) recently... which turned out to be... Schotkys ...
You knew that didn't you...
Testing a for a "real" TL072 is
presumably more difficult without a proper harness and I don't have anything remotely good enough to do that. I'm assuming there's no easy way?
Back in the days when the LM10s came out, a 741 cost me a week's pocket money. We really were that poor - and the local electronics store wasn't exactly local either!
The pride of my test equipment is a Fluke DMM that's about 30 old years old (I daren't look) that I was given when my buddy upgraded to a new fangled Fluke autoranger. Still, what ain't broke, don't need fixing!
I'll get some of those comparators ordered (thank you to those who mentioned it) - I'm happy enough to use an op amp but if there are low-cost comparators, then when in Rome! Never let it be said that I ask for advice and then ignore it!
Clearly the 393 is FAR and away more suitable with a specified 2.0v single supply voltage, there's no chance of this thing coming a gutser! (I hope I spelled that correctly this time, sorry Dave.)
So thank you one and all I hope you enjoy my sideways, self-effacing humour and I wish you all safe grounding and freedom from all things Covid!