Dumb question then...
Wikipedia says that as the resistance near the surface of the wire increases, the poynting vector tilts towards the conductor, and this is said to slow the velocity of propagation. Does this mean that the velocity factor of a wire/transmission line is not only dependent on the insulation's permeability, but also on the conductor's resistivity/skin effect? Will a thin wire propagate energy slower than a thick wire (...if that answer reverts to inductance and capacitance, ill be like )? And now I am really confused, because all that silver nitrate that I electrodeposited allegedly required electrons, something that I now hear doesn't move but at a snail's pace, (some millimeters/second? they must be really tightly packed in there!!!). So, a relation between all of this theory and Faraday's constant would be wonderful! Isn't that 6.252 x 10^18 electrons in one second for 1 amp? That's slow?
Yes!
Mind, the component that "tilts inward", is also absorbed. So, while it's slowed, it's not slowed externally.
There is still a small amount of the propagating wave that gets dragged by the line; this is improved with a little dielectric, making a Goubau line:
https://en.wikipedia.org/wiki/Goubau_lineIf you accept that resistivity, permeability and permittivity all act to increase the index of refraction, then it's easily seen that this is a case of simple refraction. Waves perfectly parallel to the surface shouldn't penetrate it, but they will in part due to evanescent waves (to use quantum terminology, the waves tunnel through the barrier as they spread out and diffract around it), and due to the dragging effect of loss (as seen in the Poynting vector, giving some radial direction). The component that dips into the surface, is refracted relative to the angle of the surface and the index of refraction; the trapped wave turns sharply inward (relatively speaking). Meanwhile, the high loss factor means attenuation is very rapid (within a wavelength or two, say), so whatever turns inward, quickly disappears as heat.
You can actually observe nulls or phase reversals inside wires or sheets (or whatever sorts of small objects), when the thickness is comparable to the skin depth; this may be due in part to phase shift, or to cancellation of the waves from both sides. (Which is why cylindrical wires for example have a skin effect distribution given by a Bessel function, whereas for the infinite half-plane, the decay is a simple exponential. Bessel functions are smooth and oscillatory; like sine, but with irregular zeroes. They aren't particularly friendly to work with (being one of those lesser used, mysterious "special functions"), but frequently show up in problems with repeated cylindrical symmetry: here, the fields AND the wire.)
As for the silver and its electrons, yes indeed! It's quite dense with electrons, and atoms are very small; this is why it takes so many coulombs of charge to deposit a sizable (some grams) amount of the stuff. Electrochemistry is rather boring, taking the pace of seconds at best, and often hours or days for typical reactions (like charging batteries, or refining metals).
To be exact, Faraday's constant is a mole of electrons, expressed in units of charge: N_A / n_e. Which comes out to 26.801 Ah/mol, so a car battery for example does about twice that, or two moles of lead, or at 208 g/mol, around a pound of lead changing oxidation state (between PbO2 / PbSO4 / Pb)! Per cell, that is. (So, about six pounds for the whole (12V) battery. The remaining 20 or so pounds being inactive -- backing, supports, interconnects.)
Tim