Some are rather rare and worth a few dollars, especially anything that's considered to be a "first".
The first Apple of course commands the big bucks and is most likely the highest valued piece of vintage technology.
the Apple Lisa (first Graphical User Interface),
almost any CP/M machine,
the Altair 8000 (early build-it-yourself kit),
the GRiD Compass (first real laptop),
most early portable computers,
etc.
As for me, nothing past the 1980s is worth anything as far as a collectible.