Is there a use for High Precision Voltage Supplies for a normal Hobby User
Almost certainly. I started with very cheap unregulated Radio Shack PSs and then went to regulated supplies by HP, Lamda and similar companies and finally to the Precision PSs made by HP and others. As your knowledge and skills increase so will your need for more
precise voltages. Particularly when you want to use a supply not as a "power supply" as a substitute for a voltage inside of circuits for troubleshooting purposes.
The better power supplies also usually feature current limiting which is also very handy when troubleshooting problems in a device. Judicious use of current limiting can prevent burning up equipment that has shorted capacitors or other shorted components or if you accidentally short out something while probing a circuit. I keep notes on everything that I work on and also include a note about how much current the device draws under normal conditions. Then the next time that I work on something similar I set the current limit of the power supply just slightly above that.
I don't use my Precision power supplies for general use but I do keep them on hand for the times that I need more precision than what an ordinary supply will give me.
Check out the HP 6104A, 6105A, 6114A 6115A and related Precision Power Supplies. They're old but still in very high demand. The manuals for those are very detailed and you can learn a lot by reading them.