Bit of constructive criticism -- I think an opportunity was missed in the video to point out that, when the 4-wire method is used, low contact resistance relays are pointless. Doesn't matter on the current supply side, and there's practically zero current on the sense side, so all around it doesn't matter. And if you're using this bit of kit without using four wires*, you lose out on performance in a big way: referring to the manual, using the 5450A in 2-wire mode at 1 ohm introduces a 25 milliohm error (90 days, after the 2 wire compensation, using test leads that were included in the calibration procedure, etc, etc), which works out to 25000 ppm, a thousand times more than the 4-wire mode specs you pointed out.
Throughout the video, whenever you were talking about contact resistances, or surprise and the non-soldered relay sockets, or the mention of amazing gold plated relay sockets, you should have heard me shouting "only in 2 wire mode!?!?". Those are not 25ppm in 2 wire mode relays or sockets. And 25ppm in 4 wire mode is achievable with a rusty nail.
Along the same lines, the relays on the top and bottom of that schematic aren't the rows and columns of a matrix (without a link to that earlier video you mentioned, I can't verify what you meant by "matrix", so I may be putting words in your mouth here, sorry), they are the separate output and sense lines, specifically separately relayed to make relay contact resistance completely, completely irrelevant**. You could connect a 1 ohm resistor using 5 ohm contact resistance relays all around, and it'd work perfectly fine**.
That minor nitpick aside, outstanding video as always; amazing components on show in there.
* Sure, you can calibrate a multimeter that only supports 2 wires, but in that case, all the plug contact resistances and lead resistances are probably going to dwarf even a half-decent relays' contacts? So again, what's the point in using million dollar relays?
** In 4 wire mode.