Hi
Welcome to the forum.
I've got a question about the simplest way to create a large amount of different DC voltage rails. I'm working on a project that needs 3-4 rails.
The transformer idea may work but is far too complicated/too much work.
Depending on what the application is, ie how much noise it can handle on the supply rails.
For very clean voltage, you need to start with a clean voltage rail and then you can drop the rails
with a number of voltage regulators.
If the application is not fussy about voltage rail noise then
Use a number of buck/boost converters such as the lm25001.
There are also some multi-rail buck converters but I do not have any part numbers at hand.