If you use a centre tapped winding into a full wave bridge to provide a + and - rail, the 6VA 18V transformer will only be good for 105mA from the +V rail. The 6VA 16V transformer is good for 120mA, (using the usual full wave bridge de-rating factor of Iac=1.6*Idc). The transformer will run somewhat cooler than it would at its max rating due to the low load on the -V rail.
However if you parallel the two windings and use a capacitively coupled bridge rectifier for the -ve rail, you can utilise the transformer more efficiently and you can get nearly 200mA of -ve rail current + 40mA of -ve rail current from the same 6VA 16V transformer, which is more than the original design's PSU could have delivered without overloading its 7.5VA 15V transformer.