Mechanical relay will work, and provided you use a double pole unit provides total load isolation when off.
The tangent is on the opto units, which have a slight leakage current when off. This is only a problem if you have a very small load, like a neon indicator, and the heater is disconnected whereupon the neon will light even if the unit is switched off by the relay. Not much to worry about, and only if you have a remote plug and socket between the relay and the heater, which means there will be a hazard if the plug is disconnected and you are working on the socket, or plug something conductive in it, thinking it is off and getting a shock. If the relay is in the heater the opto unit is better, nothing to wear out like contacts, and no switching noise if you use a zero crossing unit.