Nady,
I think many here may have misunderstood the function of your device. So I will attempt to clarify how I see it working... Correct me if I'm wrong.
You use the piezo transducer, to charge up the capacitor (0.22F). From the size of the cap, you have a great deal of energy at 2V assuming a 0.22F capacitor. I assume you need the micro to run, even if the car engine is not vibrating, so using a tripler, or some other scheme using the AC from the piezo does not meet your goals, as you need power even when the engine is not vibrating.
I would suggest taking the output from the capacitor, and use a Boost Converter stage. Boost converters can be made quite efficiently. Since efficiency is likely an important requirment, look for a Synchronous Boost Converter design. The following Wikipedia article is a decent example of a standard Boost Converter. A synchronous design will replace the diode with a switch, usually a MOSFET, to reduce power loss.
http://en.wikipedia.org/wiki/Boost_converterThere are many parts based on varying input voltages and output currents for synchronous boost converters. TI, National and many others will have parts aimed at your needs. They will do a great deal internally to keep efficiency, so I would start your search there.
Good Luck!