alm, I work with high-ish voltages a lot (vacuum tube audio equipment), and when you're used to doing that, yeah, those safety precautions become second nature. I would never wear metal jewelry or a metal watch around anything high-energy (so car batteries are right out, too - I've heard horror stories from my nurse mother about metal jewelry completing a circuit on one of those). I avoid putting both hands at once near the device, I use a clamp probe to attach to ground if possible to free a hand, and so on. I've been shocked many times at voltages much higher than 120/240 and I'm all right, but I'll be damned if I put unnecessary electrodes on my skin and touch unnecessary voltages because I can't be bothered to move a hand away and take my jewelry off.