Usually 220pF should be marked "221" and 22 as "220", but they often leave off the multiplier if it's two digits or less. Which makes "220" versus "221" ambiguous.
Unless you specifically purchased the part from a known good supplier, and have the envelope or baggie with the exact manufacturer's part number on there, and have looked up that number to verify the value... yeah, you're pretty much better off measuring it.
So your measurement is correct, 220pF it is.
Tim