Its more than just vacuums. Parts have to space rated, or MILPSEC, at the least. I don't design at this level, but I know a little about it because I was curious by the how high the cost of military parts were, and now and then some board would appear in a surplus parts bin in someplace like Apex Electronix, often its just aeronautic grade, you can get to play with them and see just how different they can be.
Cost tend to be 10-1000x the cost of a commercial part, i.e., 10c cap, becomes $10.
Electrolytics last I recall are general avoided for space and military applications. Besides temperature, there are many other parameters, key of which is various types of radiation. For mounting and assembly, shock and vibration ratings have to be highest, like warheads in missiles, given the nature of lift off to simply deliver the payload into space creates high Gs that are later dropped to zero by microgravity. Finally operational reliability requires substantial derating and a lot of cross checking, kind of like underclocking a CPU rather than overclocking it, due to effects of radiation on switching circuits.
http://nepp.nasa.gov/files/13779/Liu-Aluminum%20Capacitors.ppt * MIL-STD-975, published by NASA, focuses on selection of parts used in the design and construction of space flight hardware as well as mission-essential ground support equipment.
* MIL-STD-1547, published by the Department of Defense, is targeted to aid in the design, development and fabrication of electronic systems with long life and/or high reliability requirements while operating under the extreme conditions of space and launch vehicles.
* AS4613, published by the U.S. Navy, sets forth derating requirements for the reliable application of electronic and electromechanical parts.
* NAVSEA TE000-AB-GTP-010, published by the U.S. Navy, contains derating requirements and part selection and application information on the ten most commonly used electrical and electronic parts.
* ECSS-Q-30-11A, prepared and maintained under the authority of the Space Components Steering Board in partnership with the European Space Agency, contains derating requirements applicable to electronic, electrical and electromechanical components.
* MSFC-STD-3012, prepared by NASA's Marshall Space Flight Center, sets requirements for electrical, electronic and electromechanical parts selection, management and control for space flight and mission-essential ground support equipment for Marshall Space Flight Center programs.