From the colour codes that sounds like a Vigortronix toroidal transformer. If it is, then yes, that is correct; I have one here (50VA 2 x 0-25V) that has been powered up and has behaved itself that has been wired exactly like that on the mains side.
However, you had best check the phasing very carefully on the secondary side, as what you are suggesting sounds like wiring the secondaries in anti-phase, which is most probably not what you want.